Electrochemical Exfoliation of Graphite in Supercritical Media

The possibility of electrochemical intercalation of tetrafluoroborate anion into graphite from a supercritical electrolyte containing carbon dioxide, acetonitrile as a co-solvent, and tetrabutylammonium tetrafluoroborate has been demonstrated for the first time.

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Bibliographic Details
Published inDoklady. Physical chemistry (1991) Vol. 492; no. 2; pp. 69 - 73
Main Authors Nikiforov, A. A., Kondratenko, M. S., Kapitanova, O. O., Gallyamov, M. O.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.06.2020
Springer Nature B.V
Subjects
Acetonitrile
Carbon dioxide
Chemistry
Chemistry and Materials Science
Graphite
Physical Chemistry
highly oriented pyrolytic graphite
exfoliation
supercritical electrolyte
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Summary:The possibility of electrochemical intercalation of tetrafluoroborate anion into graphite from a supercritical electrolyte containing carbon dioxide, acetonitrile as a co-solvent, and tetrabutylammonium tetrafluoroborate has been demonstrated for the first time.
ISSN:0012-5016
1608-3121
DOI:10.1134/S0012501620060020