On the Issue of Stability of the Metastable ω Phase in Pseudo-Single-Crystalline Zirconium

• Published in: Technical physics Vol. 65; no. 1; pp. 96 - 101
• Main Authors: Egorova, L. Yu, Khlebnikova, Yu. V., Pilyugin, V. P.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 2020; Springer Nature B.V
• Subjects: Bridgman method; Classical and Continuum Physics; Configurations; Crystal growth; Crystal structure; Crystallinity; High temperature; Nucleation; Physical Science of Materials; Physics; Physics and Astronomy; Room temperature; Single crystals; Stability; Zirconium; Zirconium hydrides
• ISSN: 1063-7842; 1090-6525
• DOI: 10.1134/S1063784220010041

Pseudo-single-crystalline zirconium samples were tested in a Bridgman chamber at a temperature of 20, 70, 100, and 300°C under the same loading conditions. The aim of these tests was to examine the possibility of preservation of the metastable ω phase at elevated temperatures. It was found that stable structural configurations emerge in the process of warm deformation as a result of formation of equilibrium interphase boundaries and oriented nucleation and growth of the ω phase. These configurations enhance the stability of the ω phase after cooling and load removal. Disperse zirconium hydride particles of a variable composition (δ-ZrH 2 – x ) were identified in the sample tested at 300°C. Its high hardness, which is comparable to that of the sample tested at room temperature, is attributable to the presence of these particles.