Novel Proton Exchange Membranes Based on Sulfonated Cellulose Acetate for Fuel Cell Applications: Preparation and Characterization

• Published in: International journal of electrochemical science Vol. 11; no. 12; pp. 10150 - 10171
• Main Authors: Eldin, M.S. Mohy, Elmageed, M.H. Abd, Omer, A.M., Tamer, T.M., Yossuf, M.E., Khalifa, R.E.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.12.2016
• Subjects: Cellulose acetate; Direct methanol fuel cell; Ion exchange capacity; Methanol permeability; Proton exchange membrane; Ion exchange capacity; Methanol permeability; Direct methanol fuel cell; Cellulose acetate; Proton exchange membrane
• ISSN: 1452-3981; 1452-3981
• DOI: 10.20964/2016.12.18

A novel sulfonated cellulose acetate (SCA) membranes synthesized for the first time as a proton exchange membrane for direct membrane fuel cells (DMFCs). Cellulose acetate was activated using epichlorohydrin (ECH) followed by doping the activated membranes in sodium sulfite solution later on. The chemical structure and surface properties of SCA membranes confirmed by Infrared spectrophotometric analysis (FTIR). Morphological characterization was examined using scanning electron microscopy (SEM).The thermal stability of the prepared membranes tested by the thermogravimetric analysis (TGA). Results indicated that SCA membranes were thermally stable up to 375.72oC. Interestingly, investigating essential characters required for polyelectrolyte membrane for fuel cell application show that the ion exchange capacity (IEC) estimated in the range of 0.369– 0.996meq/g compared to 0.9 meq/g for Nafion®117. Furthermore, long membrane lifetime under oxidative conditions (Fenton's reagent), high mechanical properties (49.25N), good dimensional stability, low water and methanol uptake. In addition to, lower methanol permeability (1.729*1017- cm2/S) compared to (1.14*109-cm2/S) for Nafion®117. These results make the low-cost SCA membranes a promising polyelectrolyte for direct methanol fuel cell application.