Determining the Potential of a Silver/Silver Chloride Electrode at Different Temperatures
A simple and reliable way of determining the potential of a laboratory silver/silver chloride electrode (SSCE) is proposed, based on measuring the emf of a galvanic cell composed of silver/silver chloride and copper/copper sulfate (copper in a saturated aqueous solution of copper sulfate) electrodes...
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| Published in | Russian Journal of Physical Chemistry A Vol. 93; no. 4; pp. 770 - 773 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Moscow
Pleiades Publishing
01.04.2019
Springer Nature B.V |
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| Abstract | A simple and reliable way of determining the potential of a laboratory silver/silver chloride electrode (SSCE) is proposed, based on measuring the emf of a galvanic cell composed of silver/silver chloride and copper/copper sulfate (copper in a saturated aqueous solution of copper sulfate) electrodes. The standard thermodynamic characteristics of the reduction of a hexacyanoferrate(III) ion to hexacyanoferrate(II) in an aqueous solution are determined using the determined values of the SSCE potential. |
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| AbstractList | A simple and reliable way of determining the potential of a laboratory silver/silver chloride electrode (SSCE) is proposed, based on measuring the emf of a galvanic cell composed of silver/silver chloride and copper/copper sulfate (copper in a saturated aqueous solution of copper sulfate) electrodes. The standard thermodynamic characteristics of the reduction of a hexacyanoferrate(III) ion to hexacyanoferrate(II) in an aqueous solution are determined using the determined values of the SSCE potential. |
| Author | Lunin, V. V. Levanov, A. V. Isaikina, O. Ya |
| Author_xml | – sequence: 1 givenname: A. V. surname: Levanov fullname: Levanov, A. V. email: levanov@kge.msu.ru organization: Department of Chemistry, Moscow State University – sequence: 2 givenname: O. Ya surname: Isaikina fullname: Isaikina, O. Ya organization: Department of Chemistry, Moscow State University – sequence: 3 givenname: V. V. surname: Lunin fullname: Lunin, V. V. organization: Department of Chemistry, Moscow State University |
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| Cites_doi | 10.6028/jres.053.037 10.1021/j150563a008 10.1016/j.jelechem.2011.05.014 10.1007/s10953-016-0492-8 10.1039/J19670001205 10.1021/j100866a008 10.1002/cite.330471306 10.1016/0016-7037(77)90215-0 10.1139/v65-102 |
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| Keywords | reduction of a hexacyanoferrate(III) ion thermodynamic characteristics silver/silver chloride electrode potential |
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| SubjectTerms | Aqueous solutions Chemistry Chemistry and Materials Science Colloid Chemistry and Electrochemistry Copper Copper sulfate Electrodes Electrolytic cells Physical Chemistry Silver chloride |
| Title | Determining the Potential of a Silver/Silver Chloride Electrode at Different Temperatures |
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