Features of the Liquid-Phase Oxidation of Alkenes to Carbonyl Compounds in the Presence of Palladium Compounds

Some specific features in the liquid-phase oxidation of alkenes to ketones or aldehydes in the presence of palladium compounds (Wacker oxidation) are discussed. It is shown that selecting the appropriate conditions of the reaction (the effective compositions of the catalyst, the oxidizing agent, and...

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Bibliographic Details
Published inCatalysis in industry Vol. 13; no. 3; pp. 263 - 268
Main Authors Gogin, L. L., Zhizhina, E. G.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.07.2021
Springer Nature B.V
Subjects
Aldehydes
Alkenes
Carbonyl compounds
Carbonyls
Catalysis
Catalysis in Chemical and Petrochemical Industry
Chemistry
Chemistry and Materials Science
Composition effects
Ketones
Liquid phase oxidation
Liquid phases
Oxidation
Oxidizing agents
Palladium
Palladium compounds
palladium
Wacker oxidation
alkenes
heteropoly acids
reversible oxidizing agent
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Summary:Some specific features in the liquid-phase oxidation of alkenes to ketones or aldehydes in the presence of palladium compounds (Wacker oxidation) are discussed. It is shown that selecting the appropriate conditions of the reaction (the effective compositions of the catalyst, the oxidizing agent, and solvent) allows the selective synthesis of either ketones or aldehydes from terminal alkenes and ketones from internal alkenes.
ISSN:2070-0504
2070-0555
DOI:10.1134/S2070050421030041