Regio- and stereoselective reaction of sodium benzeneselenolate with 3-(trimethylsilyl)prop-2-ynamides

Sodium benzeneselenolate adds regio- and stereoselectively to 3-(trimethylsilyl)prop-2-yn-amides to give (Z)-3-(phenylselanyl)prop-2-enamides.

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Bibliographic Details
Published inRussian chemical bulletin Vol. 68; no. 11; pp. 2134 - 2136
Main Authors Andreev, M. V., Potapov, V. A., Musalov, M. V., Larina, L. I., Amosova, S. V.
Format Journal Article
LanguageEnglish
Published New York Springer US 01.11.2019
Springer Nature B.V
Subjects
Amides
Brief Communications
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Inorganic Chemistry
Organic Chemistry
Stereoselectivity
sodium benzeneselenolate
3-(trimethylsilyl)prop-2-ynamides
diphenyl diselenide
3-(phenylselanyl)acrylamides
nucleophilic addition
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Summary:Sodium benzeneselenolate adds regio- and stereoselectively to 3-(trimethylsilyl)prop-2-yn-amides to give (Z)-3-(phenylselanyl)prop-2-enamides.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-019-2679-9