Crystal structure of two polymorphs of molybdenyl salicylidene-2-furfuriliminate (HL1) [MoO2(L1)2]

The crystal structures of two polymorphs of molybdenyl salicylidene-2-furfuryliminate [MoO 2 (L 1 ) 2 ] have been solved by X-ray diffraction. Both complexes crystallize in centrosymmetric and non-centrosymmetric space groups ( P 2 1 / c and Р 2 1 , respectively) of monoclinic system and have simila...

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Bibliographic Details
Published inRussian journal of inorganic chemistry Vol. 62; no. 7; pp. 900 - 904
Main Authors Sergienko, V. S., Abramenko, V. L., Gorbunova, Yu. E.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.07.2017
Springer Nature B.V
Subjects
Atomic structure
Chemistry
Chemistry and Materials Science
Coordination Compounds
Crystal structure
Diffraction
Distortion
Inorganic Chemistry
Ligands
Nitrogen atoms
Oxygen atoms
X-ray diffraction
X-rays
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Summary:The crystal structures of two polymorphs of molybdenyl salicylidene-2-furfuryliminate [MoO 2 (L 1 ) 2 ] have been solved by X-ray diffraction. Both complexes crystallize in centrosymmetric and non-centrosymmetric space groups ( P 2 1 / c and Р 2 1 , respectively) of monoclinic system and have similar structures and close geometric parameters. The Мо atoms have a distorted octahedral coordination to two terminal oxo ligands in cis -positions to each other and two pairs of the oxygen atoms ( cis - to О(oxo)) and the nitrogen atoms ( trans - to О(oxo)) of two bidentate chelate ligands (L 1 ) – .
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023617070208