Synthesis and Characterization of Barium Amidoborane

Barium amidoborane was synthesized for the first time by the reaction of metal barium with ammonia borane. The compound was characterized by the methods of the solid-phase 11 B NMR and IR spectroscopy and elemental analysis. It was shown by simultaneous thermal analysis that hydrogen is the only vol...

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Bibliographic Details
Published inRussian journal of general chemistry Vol. 87; no. 12; pp. 2875 - 2877
Main Authors Shcherbina, N. A., Kazakov, I. V., Timoshkin, A. Yu
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.12.2017
Springer Nature B.V
Subjects
Ammonia
Barium
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Infrared spectroscopy
Letters to the Editor
NMR
Nuclear magnetic resonance
Thermal analysis
barium
NMR spectroscopy
amidoboranes
IR spectroscopy
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Summary:Barium amidoborane was synthesized for the first time by the reaction of metal barium with ammonia borane. The compound was characterized by the methods of the solid-phase 11 B NMR and IR spectroscopy and elemental analysis. It was shown by simultaneous thermal analysis that hydrogen is the only volatile product of barium amidoborane decomposition in the temperature range 50–240°C.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363217120192