The study of epoxidation of allyl chloride in methanol in the presence of extruded titanium containing silicalite

The liquid-phase epoxidation of allyl chloride in methanol with aqueous solution of hydrogen peroxide was conducted in the presence of extruded titanium containing silicalite and the physico-chemical features of the process were investigated. The effect of the amount of solvent, the initial ratio of...

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Bibliographic Details
Published inRussian chemical bulletin Vol. 65; no. 2; pp. 469 - 472
Main Authors Sulimov, A. V., Danov, S. M., Ovcharova, A. V., Ovcharov, A. A., Flid, V. R., Leont’eva, S. V., Flid, M. R., Trushechkina, M. A.
Format Journal Article
LanguageEnglish
Published New York Springer US 01.02.2016
Springer Nature B.V
Subjects
Allyl chloride
Aqueous solutions
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Epichlorohydrin
Epoxidation
Extrusion
Full Articles
Hydrogen peroxide
Inorganic Chemistry
Joint ventures
Liquid phases
Methanol
Organic Chemistry
Silicalite
Titanium
methanol
allyl chloride
epichlorohydrin
epoxidation
silicalite titanium
optimal conditions
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Summary:The liquid-phase epoxidation of allyl chloride in methanol with aqueous solution of hydrogen peroxide was conducted in the presence of extruded titanium containing silicalite and the physico-chemical features of the process were investigated. The effect of the amount of solvent, the initial ratio of the allyl chloride to hydrogen peroxide and the temperature of the process on the yield of the target product (epichlorohydrin) and by-products (3-chloro-1,2-propanediol and 3-chloro-1-methoxypropanol-2) was studied. Based on the obtained results, the optimum conditions of synthesis of epichlorohydrin for a laboratory scale continuous setup were recommended.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-016-1323-1