Design and synthesis of ZnCo2O4/CdS for substantially improved photocatalytic hydrogen production

• Published in: Frontiers of chemical science and engineering Vol. 17; no. 5; pp. 606 - 616
• Main Authors: Li, Xiaohong, Li, Youji, Guo, Xin, Jin, Zhiliang
• Format: Journal Article
• Language: English
• Published: Beijing Higher Education Press 01.05.2023; Springer Nature B.V
• Subjects: Charge transfer; Chemistry; Chemistry and Materials Science; Feasibility studies; Hydrogen evolution; Hydrogen production; Industrial Chemistry/Chemical Engineering; Microspheres; Nanorods; Nanospheres; Nanotechnology; Optoelectronics; Performance enhancement; Photocatalysis; Research Article; Synthesis; CdS nanorods; ZnCo; nanosphere; photocatalytic hydrogen evolution; O
• ISSN: 2095-0179; 2095-0187
• DOI: 10.1007/s11705-022-2233-4

In this study, the hydrogen evolution performance of CdS nanorods is improved using ZnCo 2 O 4 . ZnCo 2 O 4 nanospheres are synthesized using the hydrothermal and calcination methods, and CdS nanorods are synthesized using the solvothermal method. From the perspective of morphology, numerous CdS nanorods are anchored on the ZnCo 2 O 4 microspheres. According to the experimental results of photocatalytic hydrogen evolution, the final hydrogen evolution capacity of 7417.5 µmol·g −1 ·h −1 is slightly more than two times that of the single CdS, which proves the feasibility of our study. Through various characterization methods, it is proved that the composite sample has suitable optoelectronic properties. In addition, ZnCo 2 O 4 itself exhibits good conductivity and low impedance, which shortens the charge-transfer path. Overall, the introduction of ZnCo 2 O 4 expands the adsorption range of light and improves the performance of photocatalytic hydrogen evolution. This design can provide reference for developing high-efficiency photocatalysts.