Hexanuclear Na(I) complex with 3,5-dimethyl-1H-pyrazole and its anion

• Published in: Journal of structural chemistry Vol. 58; no. 4; pp. 824 - 827
• Main Authors: Vinogradova, K. A., Stabnikov, P. A., Alferova, N. I., Naumov, D. Yu, Rumyantsev, Yu. M.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 01.07.2017; Springer Nature B.V
• Subjects: Anions; Atomic; Atomic/Molecular Structure and Spectra; Brief Communications; Chemistry; Chemistry and Materials Science; Crystal structure; Inorganic Chemistry; Molecular; Optical and Plasma Physics; Physical Chemistry; Pyrazole; Solid State Physics; Volatility; pyrazolate anion; pyrazole; crystal structure; 3,5-dimethyl-1; volatility; sodium(I) complex

The crystal structure of a hexanuclear Na(I) complex based on 3,5-dimethyl-1 H -pyrazole (C 5 H 8 N 2 ) and its anion is determined (space group P 2 1 / c , a = 12.2194(5) Å, b = 24.1554(9) Å, c = 11.3311(4) Å, β = 109.942(1)°, V = 3143.99(8) Å 3 , Z = 2). The crystal structure is formed by Na 6 (C...