Hexanuclear Na(I) complex with 3,5-dimethyl-1H-pyrazole and its anion

The crystal structure of a hexanuclear Na(I) complex based on 3,5-dimethyl-1 H -pyrazole (C 5 H 8 N 2 ) and its anion is determined (space group P 2 1 / c , a = 12.2194(5) Å, b = 24.1554(9) Å, c = 11.3311(4) Å, β = 109.942(1)°, V = 3143.99(8) Å 3 , Z = 2). The crystal structure is formed by Na 6 (C...

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Published inJournal of structural chemistry Vol. 58; no. 4; pp. 824 - 827
Main Authors Vinogradova, K. A., Stabnikov, P. A., Alferova, N. I., Naumov, D. Yu, Rumyantsev, Yu. M.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.07.2017
Springer Nature B.V
Subjects
Anions
Atomic
Atomic/Molecular Structure and Spectra
Brief Communications
Chemistry
Chemistry and Materials Science
Crystal structure
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Pyrazole
Solid State Physics
Volatility
pyrazolate anion
pyrazole
crystal structure
3,5-dimethyl-1
volatility
sodium(I) complex
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Summary:The crystal structure of a hexanuclear Na(I) complex based on 3,5-dimethyl-1 H -pyrazole (C 5 H 8 N 2 ) and its anion is determined (space group P 2 1 / c , a = 12.2194(5) Å, b = 24.1554(9) Å, c = 11.3311(4) Å, β = 109.942(1)°, V = 3143.99(8) Å 3 , Z = 2). The crystal structure is formed by Na 6 (C 5 H 8 N 2 ) 4 (C 5 H 7 N 2 ) 6 molecules. Thermogravimetric studies show that the compound exhibits volatility at elevated temperatures. The compound can be used in chemical gas-phase deposition processes.
ISSN:0022-4766
1573-8779
DOI:10.1134/S002247661704028X