Synthesis of methyl(1-aminophosphonate)siloxane oligomers

A synthesis of 1-aminophosphonate derivative of methylsiloxane oligomer was developed. A methodology of the introduction of 1-aminophosphonate fragment not only into the stable siloxane structures, but also into hydrolytically unstable alkoxyfunctional organosilicon compounds was suggested.

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Bibliographic Details
Published inRussian chemical bulletin Vol. 65; no. 5; pp. 1285 - 1288
Main Authors Khairova, R. R., Milenin, S. A., Cherkaev, G. V., Stoikov, I. I., Muzafarov, A. M.
Format Journal Article
LanguageEnglish
Published New York Springer US 01.05.2016
Springer Nature B.V
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
Siloxanes
hydrosilylation
Kabachnik—Fields reaction
aminophosphonates
aminoalkylsiloxanes
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Summary:A synthesis of 1-aminophosphonate derivative of methylsiloxane oligomer was developed. A methodology of the introduction of 1-aminophosphonate fragment not only into the stable siloxane structures, but also into hydrolytically unstable alkoxyfunctional organosilicon compounds was suggested.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-016-1449-1