Organometallic alkane CH activation

The title topic is reviewed with emphasis on catalysis and on recent advances. Alkane σ complexes, Shilov chemistry and oxidative addition routes are covered. Attention is also given to σ bond metathesis, surface-bound organometallics and CH activation involving carbene complexes. Closely related re...

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 689; no. 24; pp. 4083 - 4091
Main Author Crabtree, Robert H.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 29.11.2004
Subjects
Alkane functionalization
Oxidative addition
σ Bond metathesis
Alkane functionalization
Oxidative addition
σ Bond metathesis
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Summary:The title topic is reviewed with emphasis on catalysis and on recent advances. Alkane σ complexes, Shilov chemistry and oxidative addition routes are covered. Attention is also given to σ bond metathesis, surface-bound organometallics and CH activation involving carbene complexes. Closely related reactions of non-alkane substrates such as the Murai reaction are also discussed. The title topic is reviewed with emphasis on catalysis and on recent advances. Alkane σ complexes, Shilov chemistry and oxidative addition routes are covered. Attention is also given to σ bond metathesis, surface-bound organometallics and CH activation involving carbene complexes. Closely related reactions of non-alkane substrates such as the Murai reaction are also discussed.
ISSN:0022-328X
1872-8561
DOI:10.1016/j.jorganchem.2004.07.034