Star-shaped pi-conjugated oligomers and their applications in organic electronics and photonics
Strategies for the design and construction of non-linear, 2D and 3D conjugated macromolecules are presented in this critical review. The materials, termed here as star-shaped structures, feature a core unit which may or may not provide conjugated links between arms that radiate like spokes from a ce...
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Published in | Chemical Society reviews Vol. 39; no. 7; pp. 2695 - 2728 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
England
01.07.2010
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Online Access | Get full text |
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Summary: | Strategies for the design and construction of non-linear, 2D and 3D conjugated macromolecules are presented in this critical review. The materials, termed here as star-shaped structures, feature a core unit which may or may not provide conjugated links between arms that radiate like spokes from a central axle. The arms of the macromolecules consist of linear oligomers or irregular conjugated chains lacking a formal repeat unit. The cores range from simple atoms to single or fused aromatic units and can provide a high level of symmetry to the overall structure. The physical properties of the star-shaped materials can be markedly different to their simple, linear conjugated analogues. These differences are highlighted and we report on anomalies in absorption/emission characteristics, electronic energy levels, thermal properties and morphology of thin films. We provide numerous examples for the application of star-shaped conjugated macromolecules in organic semiconductor devices; a comparison of their device performance with those comprising analogous linear systems provides clear evidence that the star-shaped compounds are an important class of material in organic electronics. Moreover, these structures are monodisperse, well-defined, discrete molecules with 100% synthetic reproducibility, and possess high purity and excellent solubility in common organic solvents. They feature many of the attributes of plastic materials (good film-forming properties, thermal stability, flexibility) and are therefore extremely attractive alternatives to conjugated polymers (210 references). |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0306-0012 1460-4744 |
DOI: | 10.1039/b918154g |