Slow large-scale supramolecular structuring as a cause of kinetic anomalies in the liquid-phase oxidation with nitric acid

Isothermal calorimetry, static and dynamic light scattering, and NMR spectroscopy studies provided evidence for slow formation of large associates of solvates in aqueous solutions of nitric acid, which makes it possible to attribute the anomalous kinetic features in the oxidation of acetone to the s...

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Bibliographic Details
Published inRussian chemical bulletin Vol. 65; no. 4; pp. 984 - 992
Main Authors Lagodzinskaya, G. V., Laptinskaya, T. V., Kazakov, A. I., Kurochkina, L. S., Manelis, G. B.
Format Journal Article
LanguageEnglish
Published New York Springer US 01.04.2016
Springer Nature B.V
Subjects
Anomalies
Aqueous solutions
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Liquid phase oxidation
Liquid phases
Nitric acid
NMR spectroscopy
Organic Chemistry
Photon correlation spectroscopy
nitric acid
dynamic light scattering
acetone
supramolecular structure of the liquid reaction medium
oxidation
isothermal calorimetry
kinetics
mechanism
NMR spectroscopy
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Summary:Isothermal calorimetry, static and dynamic light scattering, and NMR spectroscopy studies provided evidence for slow formation of large associates of solvates in aqueous solutions of nitric acid, which makes it possible to attribute the anomalous kinetic features in the oxidation of acetone to the supramolecular mechanism of the reaction.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-016-1401-4