Natural Dyes from Ornamental Plants as Sensitizers for Dye-Sensitized Solar Cells (DSSCs): A Review on the Structure-Activity Relationships (SARs) between Power Conversion Efficiencies and Chemical Constituents

• Published in: Russian journal of applied chemistry Vol. 94; no. 12; pp. 1561 - 1576
• Main Authors: Nixon, Peter Daniel, Baby, Ruby, Kumar, Nallapaneni Manoj, Ananthi, Nallamuthu
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 01.12.2021; Springer Nature B.V
• Subjects: Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Constituents; Dye-sensitized solar cells; Dyes; Energy conversion efficiency; Industrial Chemistry/Chemical Engineering; Photovoltaic cells; Reviews; Thin films; Toxicity; power conversion efficiency; crotons; dye-sensitized solar cells; structure-activity relationships (SARs); ornamental plants; DSSC
• ISSN: 1070-4272; 1608-3296
• DOI: 10.1134/S1070427221120016

Among the various types of solar cells, the dye-sensitized solar cells (DSSCs) are a type of thin-film solar photovoltaic cells that have been the subject of intense research for over two decades. The DSSCs are being developed using various photosensitizers, both natural and synthetic dyes; however, in recent years, natural dyes use in DSSCs is getting more attention due to the reduced toxicity levels and preparation cost. Apart from these, the simple preparation methodology and manufacturing ease also favour the DSSCs. Though the DSSCs constructed by utilizing natural dyes are becoming popular, the research on dyes extracted from ornamental plants is significantly less. Also, it appears to be critical in plant selection to ensure better power conversion efficiencies as they mainly depend on the chemical constituents present in the dye. Hence, this study aims to review the past works and provide a consolidated decision on plant selection. First, the DSSCs using the natural extracts of various parts of ornamental plants as sensitizers were reported to give better power conversion efficiencies (PCE) than the DSSCs constructed using the extracts of non-ornamental plants. Second, we disused the electrical characteristics and efficiencies of DSSCs constructed using the extracts of ornamental plants. Third, the structure-activity relationships (SARs) of the constituents present in the extracted dyes of ornamental plants with respect to the overall PCE of the fabricated DSSCs is discussed in detail. Overall, this article provides an in-depth review of 50 plus ornamental plants for DSSC construction.