Synthesis of 4-(dibromomethyl)benzenecarbaldehyde and its reactions with N- and O-nucleophiles

4-(Dibromomethyl)benzenecarbaldehyde was first synthesized and its preparation method jointly with terephthalic aldehyde was developed. Its reactions with O- and N-nucleophiles were studied: the reaction of this aldehyde with trialkyl orthoformates results in the formation of acetals while reacting...

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Bibliographic Details
Published inRussian chemical bulletin Vol. 65; no. 1; pp. 191 - 194
Main Authors Gazizov, M. B., Ivanova, S. Yu, Karimova, R. F., Bagauva, L. R., Gazizova, K. S., Karimova, A. A.
Format Journal Article
LanguageEnglish
Published New York Springer US 2016
Springer Nature B.V
Subjects
Benzene
Chemical reactions
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
4-(dibromomethyl)benzenecarbaldehyde
trimethyl phosphate
preparation method
imines containing acetal group
acetals
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Summary:4-(Dibromomethyl)benzenecarbaldehyde was first synthesized and its preparation method jointly with terephthalic aldehyde was developed. Its reactions with O- and N-nucleophiles were studied: the reaction of this aldehyde with trialkyl orthoformates results in the formation of acetals while reacting with primary amines it forms imines, including those containing an additional acetal group.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-016-1282-6