Research on Selective Oxidation of Carbon and Aluminum with Introduction of CO2 in RH Refining of Low-Carbon Steel Process

• Published in: Metallurgical and materials transactions. B, Process metallurgy and materials processing science Vol. 49; no. 6; pp. 3544 - 3551
• Main Authors: Han, Baochen, Zhu, Rong, Zhu, Yiqiang, Liu, Runzao, Wu, Wenhe, Li, Qiang, Wei, Guangsheng
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.12.2018; Springer Nature B.V
• Subjects: Aluminum; Aluminum base alloys; Carbon dioxide; Characterization and Evaluation of Materials; Chemistry and Materials Science; Degassing; Iron and steel industry; Ladle metallurgy; Low carbon steel; Low carbon steels; Materials Science; Metallic Materials; Nanotechnology; Oxidation; Steel industry; Structural Materials; Surfaces and Interfaces; Thermodynamic equilibrium; Thin Films; Initial Aluminum Content; Vacuum Degree; Molten Steel; Oxidation Zone; Low Temperature Drop
• ISSN: 1073-5615; 1543-1916
• DOI: 10.1007/s11663-018-1417-2

The injection of CO 2 during the Rheinstahl–Heraeus (RH) refining process as a lifting gas is a new attempt for the steel industry, and can promote refining effect and realize the utilization of CO 2 as a resource. In the present study, the thermodynamic equilibrium of the RH refining process through CO 2 injection instead of Ar was calculated using FactSage software. A selective oxidation sequence of [C] and [Al] with CO 2 was studied and analyzed under the RH refining temperature and vacuum degree. In addition, the oxidation zones of carbon and aluminum were both defined. Industrial trials were preliminarily conducted to verify the above theory. The results show that CO 2 has the potential to be used to refine low-carbon steel in RH, but its refining effect is affected by the [Al] content in steel. By reducing the additive amount of aluminum alloy in the ladle furnace and replenishing the aluminum during the late stage of the RH refining process, CO 2 injection can achieve a lower temperature drop of molten steel and a better refining effect than Ar during the RH degassing process.