Molecular and crystal structure of a cationic dinitrosyl iron complex with 1,3-dimethylthiourea

A new dinitrosyl iron complex of the composition [Fe(SC(NHCH 3 ) 2 ) 2 (NO) 2 ]Cl ( I ) is obtained by direct nitrosylation of ferrous sulfate and a hydrochloric acid solution of 1,3-dimethylthiourea. The characteristic features of the molecular and crystal structure of complex I is determined by si...

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Bibliographic Details
Published inJournal of structural chemistry Vol. 58; no. 2; pp. 353 - 355
Main Authors Shmatko, N. Yu, Korchagin, D. V., Shilov, G. V., Sanina, N. A., Aldoshin, S. M.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.03.2017
Springer Nature B.V
Subjects
Atomic
Atomic/Molecular Structure and Spectra
Brief Communications
Chemistry
Chemistry and Materials Science
Crystal structure
Hydrochloric acid
Inorganic Chemistry
Iron
Iron sulfates
Molecular
Molecular structure
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
single crystal X-ray diffraction (XRD)
dinitrosyl iron complexes
1,3-dimethylthiourea
nitric oxide (NO)
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Summary:A new dinitrosyl iron complex of the composition [Fe(SC(NHCH 3 ) 2 ) 2 (NO) 2 ]Cl ( I ) is obtained by direct nitrosylation of ferrous sulfate and a hydrochloric acid solution of 1,3-dimethylthiourea. The characteristic features of the molecular and crystal structure of complex I is determined by single crystal X-ray diffraction analysis.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476617020172