Synthesis of Multidentate Chalcogen-Containing Ligands Based on Bis(2-bromoethyl) Sulfide

Derivatives of bis(2-bromoethyl) sulfide of the general formula (RSCH 2 CH 2 ) 2 S, where R = Me, Et, Pr, i -Pr, Bu, i -Bu, t -Bu, C 6 H 13 , Cy, Ph, and Bn, were synthesized and characterized by IR and 1 H and 13 C NMR spectra. The synthesized compounds are potential electron-donating multidentate...

Full description

Saved in:
Bibliographic Details
Published inRussian journal of organic chemistry Vol. 57; no. 10; pp. 1662 - 1667
Main Authors Bezborodov, V. A., Babenko, I. A., Ratovskii, G. V., Ushakov, I. A., Vilms, A. I.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.10.2021
Springer Nature
Springer Nature B.V
Subjects
Chemistry
Chemistry and Materials Science
Chemistry, Organic
Coordination compounds
Ligands
NMR
Nuclear magnetic resonance
Organic Chemistry
Physical Sciences
Science & Technology
Synthesis
organic sulfides and disulfides
bis(2-bromoethyl) sulfide
multidentate ligands
thiols
MOLYBDENUM(II)
ETHYLENE
DONOR LIGANDS
COMPLEXES
CRYSTAL-STRUCTURES
DICHALCOGENIDES
TUNGSTEN(II)
Online AccessGet full text

Cover

More Information
Summary:Derivatives of bis(2-bromoethyl) sulfide of the general formula (RSCH 2 CH 2 ) 2 S, where R = Me, Et, Pr, i -Pr, Bu, i -Bu, t -Bu, C 6 H 13 , Cy, Ph, and Bn, were synthesized and characterized by IR and 1 H and 13 C NMR spectra. The synthesized compounds are potential electron-donating multidentate ligands that are promising for the preparation of coordination compounds and as components of catalytic systems for catalytic transformations of ethylene.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428021100158