Rate Constant of the Reaction between Ozone and Chloride Ion in an Aqueous Solution According to a Mechanism of Oxygen Atom Transfer

The effect of concentrations of Cl – and H + ions, temperature, and ionic strength on the rate constant of the reaction between O 3 and Cl – (aq) is studied experimentally. The reaction proceeds according to a mechanism of oxygen transfer and results in the formation of molecular chlorine in acidic...

Full description

Saved in:
Bibliographic Details
Published inRussian Journal of Physical Chemistry A Vol. 93; no. 6; pp. 1045 - 1048
Main Authors Levanov, A. V., Isaikina, O. Ya, Lunin, V. V.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.06.2019
Springer Nature B.V
Subjects
Aqueous solutions
Chemical Kinetics and Catalysis
Chemistry
Chemistry and Materials Science
Chloride ions
Chlorine
Dependence
Oxygen transfer
Physical Chemistry
chloride ion
rate constant
ionic strength
molecular chlorine
ozone
Online AccessGet full text

Cover

More Information
Summary:The effect of concentrations of Cl – and H + ions, temperature, and ionic strength on the rate constant of the reaction between O 3 and Cl – (aq) is studied experimentally. The reaction proceeds according to a mechanism of oxygen transfer and results in the formation of molecular chlorine in acidic medium. A formula is proposed for calculating the dependence of the rate constant on these factors.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024419060189