Solution Combustion Synthesis of Lithium Cobalt Oxide – Cathode Material for Lithium-Ion Batteries

• Published in: International journal of electrochemical science Vol. 14; no. 3; pp. 2965 - 2983
• Main Authors: Zhuravlev, Victor D., Shikhovtseva, Anna V., Ermakova, Larisa V., Evshchik, Elizaveta Yu, Sherstobitova, Elena A., Novikov, Dmitry V., Bushkova, Olga V., Dobrovolsky, Yuri A.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.03.2019
• Subjects: lithium cobalt oxide; lithium-ion batteries; solution combustion synthesis; lithium cobalt oxide; lithium-ion batteries; solution combustion synthesis
• ISSN: 1452-3981; 1452-3981
• DOI: 10.20964/2019.03.79

A simple but novel solution combustion synthesis (SCS) technique suitable for LiCoO2 scale production was developed. Citric acid was used together with glycine to slow down the combustion rate; cobalt(II) nitrate was partially replaced with cobalt(II) carbonate hydroxide to reduce the heating of the off-gases using the excess heat of the redox reaction. As a result, no open flame or eruption of the powder product out of the reactor was observed; the rapid SCS process occurring in the desired non-turbulent mode is suitable for scaling. The influence of the ratios cobalt(II) nitrate/cobalt(II) carbonate hydroxide and glycine/citric acid on the LiCoO2 powder product properties was examined along with the influence of the post-combustion annealing conditions and pH of the precursor solution. The thus-obtained LiCoO2 powders were characterised by X-ray diffraction, scanning electron microscopy and particle size distribution analysis. Testing of the electrochemical behaviour of the LiCoO2 powders was performed in Li/LiCoO2test cells having 1M LiDFOB in EC/DMC (1:1, wt.) as an electrolyte. The results confirmed the high electrochemical activity of the SCS-derived LiCoO2powders; the best samples exhibited a discharge capacity ≥150 mAh g-1 and coulombic efficiency ≥99.5 % following 30 cycles at C/10 rate.