Hysteretic spin crossover in isomeric iron(ii) complexes

Two mononuclear iron(ii) complexes with isomeric N,N,N-tridentate pyrimidine-based ligands were synthesized. Both complexes show reproducible hysteretic spin crossover. Low spin state to high spin state switching is cooperative due to autocatalysis.

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Bibliographic Details
Published inDalton transactions : an international journal of inorganic chemistry Vol. 47; no. 29; pp. 9585 - 9591
Main Authors Bushuev, Mark B, Krivopalov, Viktor P, Nikolaenkova, Elena B, Vinogradova, Katerina A, Gatilov, Yuri V
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2018
Subjects
Autocatalysis
Coordination compounds
Hysteresis
Iron
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Summary:Two mononuclear iron(ii) complexes with isomeric N,N,N-tridentate pyrimidine-based ligands were synthesized. Both complexes show reproducible hysteretic spin crossover. Low spin state to high spin state switching is cooperative due to autocatalysis.
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content type line 23
ISSN:1477-9226
1477-9234
DOI:10.1039/c8dt02223b