Recent advances in nickel-catalyzed C-C and C-N bond formation via HA and ADC reactions

In recent times, earth-abundant 3d-transition-metal catalysts have attracted much attention in contemporary catalysis. They have been widely employed as suitable alternatives to their counterparts noble metals. In particular, nickel catalysts provide distinctive redox properties; thus, their efficie...

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Published inOrganic & biomolecular chemistry Vol. 19; no. 19; pp. 4213 - 4227
Main Authors Subaramanian, Murugan, Sivakumar, Ganesan, Balaraman, Ekambaram
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 21.05.2021
Subjects
Catalysis
Catalysts
Chemical reactions
Dehydrogenation
Heavy metals
Nickel
Noble metals
Redox properties
Transition metals
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Summary:In recent times, earth-abundant 3d-transition-metal catalysts have attracted much attention in contemporary catalysis. They have been widely employed as suitable alternatives to their counterparts noble metals. In particular, nickel catalysts provide distinctive redox properties; thus, their efficiency in sustainable organic transformations is manifold. In this review article, recent advances in nickel-catalyzed hydrogen auto-transfer (HA) and acceptorless dehydrogenative coupling (ADC) reactions for the construction of C-C and C-N bonds have been discussed.
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ISSN:1477-0520
1477-0539
DOI:10.1039/d1ob00080b