Preparation of Rh-TPPTS complex intercalated layered double hydroxide and influences of host and guest compositions on its catalytic performances in hydroformylation reaction

Based on the concept of intercalation chemistry of layered double hydroxides （LDHs）, RhCI（CO）（TPPTS）2 （TPPTS： P（m-C6H4SO3Na）3） and TPPTS co-intercalated LDHs were successfully synthesized by in situ complexation method. Characterizations of structure and composition of composite materials by powder...

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Bibliographic Details
Published inChinese science bulletin Vol. 53; no. 9; pp. 1329 - 1336
Main Authors Zhang, Xian, Lu, Jun, Jin, Lan, Wei, Min
Format Journal Article
LanguageEnglish
Published Heidelberg SP Science in China Press 01.05.2008
Subjects
Chemistry/Food Science
Earth Sciences
Engineering
Humanities and Social Sciences
Life Sciences
multidisciplinary
Physics
Science
Science (multidisciplinary)
催化剂
加氢甲酰基化
氢氧化物
络合物
layered double hydroxides
supported catalyst
hydroformylation
RhCl(CO)(TPPTS)
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Summary:Based on the concept of intercalation chemistry of layered double hydroxides （LDHs）, RhCI（CO）（TPPTS）2 （TPPTS： P（m-C6H4SO3Na）3） and TPPTS co-intercalated LDHs were successfully synthesized by in situ complexation method. Characterizations of structure and composition of composite materials by powder XRD, FT-IR, and ICP-AES techniques confirmed the supramolecular structures of the catalytic species intercalated LDHs. The correlation between catalytic performance of intercalated catalyst and the composition of both host layers and interlayer guest species was also investigated.
Bibliography:11-1785/N
layered double hydroxides, hydroformylation, supported catalyst, RhCI（CO）（TPPTS）2
O6
ISSN:1001-6538
2095-9273
1861-9541
2095-9281
DOI:10.1007/s11434-008-0071-5