Simple synthesis of SiGe@C porous microparticles as high-rate anode materials for lithium-ion batteries

• Published in: RSC advances Vol. 7; no. 54; pp. 33837 - 33842
• Main Authors: Zhang, Yaguang, Du, Ning, Xiao, Chengmao, Wu, Shali, Chen, Yifan, Lin, Yangfan, Jiang, Jinwei, He, Yuanhong, Yang, Deren
• Format: Journal Article
• Language: English
• Published: 01.01.2017
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/c7ra04364c

We report the synthesis of SiGe@C porous microparticles (PoSiGe@C) via the decomposition of Mg 2 Si/Mg 2 Ge composites, acid pickling and subsequent carbon coating processes, respectively. The content of Ge can be tuned by the initial ratio of Mg 2 Si and Mg 2 Ge in the composite. The as-synthesized PoSiGe@C has been used as the anode material of lithium-ion batteries, which shows an enhanced cyclic and rate performance compared to bare Si, PoSiGe as well as PoSi@C porous microparticles. Briefly, the PoSiGe@C delivers a good cycling stability with 70% capacity retention after 400 cycles and only 0.075% capacity loss per cycle at the current density of 0.8 A g −1 . Furthermore, super rate capability is also expressed by the PoSiGe@C. The unique porous structure, and synergistic effect of Si and Ge, may lead to the inherent high lithium-ion diffusivity and electrical conductivity of Ge, and good volume alleviation, which results in the good electrochemical performance. We synthesize the PoSiGe@C via the decomposition of Mg 2 Si/Mg 2 Ge composites, acid pickling and subsequent carbon coating processes, which show excellent cycling and rate performance as anode materials for lithium-ion batteries.