Metal-free difunctionalization of alkynes leading to alkenyl dithiocyanates and alkenyl diselenocyanates at room temperature
A simple and practical method for the synthesis of alkenyl dithiocyanates and alkenyl diselenocyanates has been developed via stereoselective difunctionalization of alkynes with NaSCN or KSeCN at room temperature. Through this methodology, a series of alkenyl dithiocyanates and alkenyl diselenocyana...
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Published in | Organic & biomolecular chemistry Vol. 16; no. 46; pp. 9064 - 9068 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
CAMBRIDGE
Royal Soc Chemistry
28.11.2018
Royal Society of Chemistry |
Subjects | |
Online Access | Get full text |
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Summary: | A simple and practical method for the synthesis of alkenyl dithiocyanates and alkenyl diselenocyanates has been developed
via
stereoselective difunctionalization of alkynes with NaSCN or KSeCN at room temperature. Through this methodology, a series of alkenyl dithiocyanates and alkenyl diselenocyanates could be efficiently and conveniently obtained in moderate to good yields under mild and metal-free conditions by the simple use of oxone and PhI(OAc)
2
as the oxidants. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
ISSN: | 1477-0520 1477-0539 1477-0539 |
DOI: | 10.1039/C8OB02368A |