Cobalt sulfide nanoparticles restricted in 3D hollow cobalt tungstate nitrogen-doped carbon frameworks incubating stable interfaces for Li-ion storage

• Published in: Electrochimica acta Vol. 431; p. 141134
• Main Authors: Zheng, Yun, Xu, Yang, Guo, Junpo, Li, Jianding, Shen, Jingjun, Guo, Yan, Bao, Xiaozhi, Huang, Yike, Zhang, Qi, Xu, Jincheng, Wu, Jue, Ian, Hou, Shao, Huaiyu
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.11.2022
• Subjects: Hierarchical nanostructures; In-situ EIS; Li-ion transfer and storage; MOFs; Ostwald ripening; Li-ion transfer and storage; MOFs; In-situ EIS; Ostwald ripening; Hierarchical nanostructures
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2022.141134

•Hierarchical nanostructure Co9S8@CoWO4/nitrogen-doped carbon was obtained based on Ostwald ripening mechanism.•Ingenious yolk-shell configuration boosts Li-ion transport and buffers volume expansion during lithiation/delithiation.•Co9S8@CoWO4/nitrogen-doped carbon anode delivers an ultrahigh specific capacity (1053 mAh·g−1 at 500 mA·g−1).•In-situ EIS and Ex-situ SEM were conducted to confirm the successful incubating of stable interfaces. Hierarchical nanostructures that comprise multiple tiers of structural subunits and diverse chemical components can provide more active storage sites and relieve the micro-strain due to volumetric change than solid structures in LIBs. In this work, we designed the facile preparation of a yolk-shell structure based on Ostwald ripening for steady lithium-ion storage with Co9S8@CoWO4/nitrogen-doped carbon nanohybrids (YS-Co9S8@CoWO4-NC) as anodes. This yolk-shell configuration design not only accelerated the diffusion of lithium-ion during the lithiation process but also constructed stable interfaces for achieving more steady cycling. It consequently delivered long cycle stability (780 mAh·g−1 after 250 cycles at 1000 mA·g−1) and excellent rate capacities (1023, 767 mAh·g−1 at 100, 2000 mA·g−1, respectively). Furthermore, in-situ electrochemical impedance spectroscopy was successfully implemented to monitor interface properties by simultaneously recording the impedance during discharging and charging processes. The incubating of stable interfacial layers was further confirmed by ex-situ SEM. These results fully affirmed the contribution of hierarchical nanostructures to the construction of stable interfaces, achieving long cycle Li-ion storage. [Display omitted]