In situ evaluation of interfacial affinity in CeO2 based hybrid nanoparticles by pulsed field gradient NMR

Complexation affinity of laurate ligands (C(12)H(23)O(2)) grafted onto the surface of cerium(IV) oxide nanoparticles can be probed and quantified in situ, by pulsed field gradient (1)H NMR through the dependence of the diffusion coefficient on the size of a species.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 8; p. 1019
Main Authors Ribot, François, Escax, Virginie, Roiland, Claire, Sanchez, Clément, Martins, José C, Biesemans, Monique, Verbruggen, Ingrid, Willem, Rudolph
Format Journal Article
LanguageEnglish
Published England 28.02.2005
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Summary:Complexation affinity of laurate ligands (C(12)H(23)O(2)) grafted onto the surface of cerium(IV) oxide nanoparticles can be probed and quantified in situ, by pulsed field gradient (1)H NMR through the dependence of the diffusion coefficient on the size of a species.
ISSN:1359-7345
DOI:10.1039/b411629a