Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks
We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML2(NO3)2]n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mi...
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Published in | Chemical communications (Cambridge, England) Vol. 55; no. 10; pp. 1454 - 1457 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
England
Royal Society of Chemistry
29.01.2019
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Subjects | |
Online Access | Get full text |
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Summary: | We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML2(NO3)2]n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel-inclined 2D → 3D polycatenation). |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c8cc09152h |