Zinc-catalyzed transamidation and esterification of N-benzoyl cytosine via C-N bond cleavage

We have utilized N-benzoyl cytosine for efficient transamidation and esterification via catalytic C-N bond cleavage. The one-pot strategy involves the reaction of secondary amide with various aliphatic or aromatic amines and alcohols in the presence of zinc triflate and DTBP, affording diverse amide...

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Published inOrganic & biomolecular chemistry Vol. 21; no. 25; pp. 5176 - 5180
Main Authors Gaware, Sujeet, Chatterjee, Rana, Kapdi, Anant R. R., Dandela, Rambabu
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 28.06.2023
Royal Society of Chemistry
Subjects
Alcohols
Amides
Amines
Chemistry
Chemistry, Organic
Cleavage
Cytosine
Esterification
Esters
Physical Sciences
Science & Technology
Zinc
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Summary:We have utilized N-benzoyl cytosine for efficient transamidation and esterification via catalytic C-N bond cleavage. The one-pot strategy involves the reaction of secondary amide with various aliphatic or aromatic amines and alcohols in the presence of zinc triflate and DTBP, affording diverse amides and esters in excellent yields.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1477-0520
1477-0539
DOI:10.1039/d3ob00697b