Luminescent cluster-organic frameworks constructed from predesigned supertetrahedral {} secondary building units

3d-4f heterometallic supertetrahedral clusters with the formula of Ln 4 Zn 6 (μ 6 -O)L 4 (CH 3 COO) 6 (NO 3 ) 4 (CH 3 OH) 4 (H 2 O) 2 (1-Ln, Ln = Eu, Gd, Tb, H 3 L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) have been successfully introduced as stable secondary building units (SBUs) to con...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 57; no. 56; pp. 6927 - 693
Main Authors Ge, Rui, Liu, Jin-Hua, Li, Xin-Hao, Li, Ling-Yun, Sun, Yan-Qiong, Li, Zhikai, Li, Xin-Xiong, Zheng, Shou-Tian
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 18.07.2021
Subjects
Clusters
Crystallography
Gadolinium
Optical materials
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Summary:3d-4f heterometallic supertetrahedral clusters with the formula of Ln 4 Zn 6 (μ 6 -O)L 4 (CH 3 COO) 6 (NO 3 ) 4 (CH 3 OH) 4 (H 2 O) 2 (1-Ln, Ln = Eu, Gd, Tb, H 3 L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) have been successfully introduced as stable secondary building units (SBUs) to construct new cluster-organic frameworks with tunable emission, demonstrating a promising strategy for developing new optical materials. A new type of 3d-4f supertetrahedral cluster has been introduced for the first time as a secondary building unit to construct luminescent cluster-organic frameworks with tunable emission, demonstrating a promising strategy for new optical materials.
Bibliography:2076140
10.1039/d1cc02727a
For ESI and crystallographic data in CIF or other electronic format see DOI
Electronic supplementary information (ESI) available: Experimental details, additional characterizations, tables, and figures. CCDC
2076012
and
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc02727a