Metal-free recycling of waste polyethylene terephthalate mediated by TBD protic ionic salts: the crucial role of anionic ligands

• Published in: Physical chemistry chemical physics : PCCP Vol. 25; no. 41; pp. 27936 - 27941
• Main Authors: Zhu, Chenxi, Yang, Linlin, Chen, Chenhui, Zeng, Guixiang, Jiang, Wei
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 25.10.2023
• Subjects: Carbonyl groups; Carbonyls; Density functional theory; Ethylene glycol; Glycolysis; Ligands; Polyethylene terephthalate; Protons; Recycling
• ISSN: 1463-9076; 1463-9084; 1463-9084
• DOI: 10.1039/d3cp03590e

The structure-activity relationships of 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) based protic ionic salts for polyethylene terephthalate (PET) glycolysis by ethylene glycol (EG) were comprehensively investigated through theoretical prediction and experimental verification. The proton capture ability of the anionic ligand from EG is positively correlated with the activity of the catalyst, as the generation of EG − was crucial for the chain breaking reaction via nucleophilic attack on the carbonyl group. Furthermore, density functional theory calculations demonstrated that the HTBD cation and anionic ligands work in a cooperative manner in the PET glycolysis reaction, where the ligands abstract a proton from EG to generate EG − and provide a proton to produce the bis(hydroxyalkyl)terephthalate (BHET) product. The rate-determining step is the nucleophilic attack step, where the Gibbs energy barriers (Δ G ≠ ) increase in the order of 29.7 kcal mol −1 (HTBD-OAc) < 30.2 kcal mol −1 (HTBD-CH 3 CH 2 COO) < 31.4 kcal mol −1 (HTBD-HCOO) < 35.7 kcal mol −1 (HTBD-CH 3 COCOO) < 36.9 kcal mol −1 (HTBD-NO 3 ). This is confirmed from the experimental results that the BHET yields decrease in the order of 84.8% (HTBD-OAc) > 82.4% (HTBD-CH 3 CH 2 COO) > 80.2% (HTBD-HCOO) > 73.6% (HTBD-CH 3 COCOO) > 4.7% (HTBD-NO 3 ). These findings offer valuable guidance for designing more efficient metal-free protic ionic salts, promoting sustainable PET recycling. The structure-activity relationships of TBD based protic ionic salts for PET glycolysis by EG were comprehensively investigated through theoretical prediction and experimental verification.