Metalated covalent organic frameworks: from synthetic strategies to diverse applications
Covalent organic frameworks (COFs) are a class of organic crystalline porous materials discovered in the early 21st century that have become an attractive class of emerging materials due to their high crystallinity, intrinsic porosity, structural regularity, diverse functionality, design flexibility...
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| Published in | Chemical Society reviews Vol. 51; no. 15; pp. 637 - 6416 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Royal Society of Chemistry
01.08.2022
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| Subjects | |
| Online Access | Get full text |
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| Summary: | Covalent organic frameworks (COFs) are a class of organic crystalline porous materials discovered in the early 21st century that have become an attractive class of emerging materials due to their high crystallinity, intrinsic porosity, structural regularity, diverse functionality, design flexibility, and outstanding stability. However, many chemical and physical properties strongly depend on the presence of metal ions in materials for advanced applications, but metal-free COFs do not have these properties and are therefore excluded from such applications. Metalated COFs formed by combining COFs with metal ions, while retaining the advantages of COFs, have additional intriguing properties and applications, and have attracted considerable attention over the past decade. This review presents all aspects of metalated COFs, from synthetic strategies to various applications, in the hope of promoting the continued development of this young field.
This review highlights the recent advances of metalated covalent organic frameworks, including synthetic strategies and applications, and discusses the current challenges and future directions. |
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| Bibliography: | Prof. Dr Yu-Bin Dong is the Chang Jiang Scholar of chemistry at Shandong Normal University. He obtained his PhD from Nankai University (under Prof. Li-Cheng Song) in 1996. He then joined Prof. Andreas Mayr's group at The University of Hong Kong and Prof. Hans-Conrad zur Loye's group at the University of South Carolina from 1996 to 2000, and was promoted to full professor at Shandong Normal University in 2000. He is the author of over 200 peer-reviewed publications. His current research interests are mainly focused on MOF and COF materials and their applications in catalysis, sensing, bioimaging, and cancer treatment. Le-Le Zhou received her master's degree in organic chemistry from Shandong Normal University under the supervision of Prof. Yu-Bin Dong in 2018. Then, she worked as a lecturer at the School of Chemical and Biological Engineering, Qilu Institute of Technology, from 2018 to 2020. Currently, she is a PhD student under the supervision of Prof. Yu-Bin Dong. Her research interests are advanced materials for preventing and treating tumors. Qun Guan is currently a PhD student. He received his bachelor's degree in chemistry from the University of Jinan in 2015. He received his master's degree in organic chemistry from Shandong Normal University under the guidance of Prof. Yu-Bin Dong in 2019 and has subsequently continued his PhD studies. His research focuses on nanoscale COFs for cancer diagnosis and therapeutics. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 ObjectType-Review-3 content type line 23 |
| ISSN: | 0306-0012 1460-4744 1460-4744 |
| DOI: | 10.1039/d1cs00983d |