Mixed-ligand metal-organic frameworks as an effective photocatalyst for selective oxidation reaction

By incorporating tetrakis(4-carboxyphenyl)porphyrin and bis(3,5-dicarboxyphenyl)pyridine into one single metal-organic framework (MOF), a multifunctional mixed-ligand Zn- MIX with large pores was obtained. Under visible-light irradiation, Zn- MIX exhibits high photocatalytic activity for the oxidati...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 59; no. 75; pp. 1122 - 11223
Main Authors Li, Hanning, Yang, Yang, Jing, Xu, He, Cheng, Duan, Chunying
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 19.09.2023
Subjects
Amines
Catalytic activity
Ligands
Light irradiation
Metal-organic frameworks
Oxidation
Photocatalysis
Porphyrins
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Summary:By incorporating tetrakis(4-carboxyphenyl)porphyrin and bis(3,5-dicarboxyphenyl)pyridine into one single metal-organic framework (MOF), a multifunctional mixed-ligand Zn- MIX with large pores was obtained. Under visible-light irradiation, Zn- MIX exhibits high photocatalytic activity for the oxidation of amines and sulfides. Mixed-ligand Zn- MIX was obtained for the photooxidation of amines and sulfides, which presents a promising strategy for the design of multi-component MOFs with considerable photocatalytic activity.
Bibliography:Electronic supplementary information (ESI) available. CCDC
For ESI and crystallographic data in CIF or other electronic format see DOI
https://doi.org/10.1039/d3cc02839a
2266328
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc02839a