Determination of water activities, osmotic and activity coefficients of the system NH4NO3-LiNO3-H2O at the temperature 298.15 K

• Published in: Calphad Vol. 28; no. 3; pp. 321 - 327
• Main Authors: MAROUANI, Mohamed, EL GUENDOUZI, Mohamed
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier 01.09.2004
• Subjects: Chemical thermodynamics; Chemistry; Exact sciences and technology; General and physical chemistry; General. Theory; Water; Ternary system; Water activity; Thermodynamic model; Electrolyte solution; Phase diagram; Lithium nitrate; Ammonium nitrate; Activity coefficient; Aqueous solution; Osmotic coefficient; Thermodynamic properties
• ISSN: 0364-5916; 1873-2984
• DOI: 10.1016/j.calphad.2004.10.002

The water activities of the mixed aqueous electrolyte ((y) NH4NO3 + (1 - y) LiNO3)}(aq) are measured at total molalities from 0.2 mol kg -I to about saturation for different ionic-strength fractions y of NH4NO3 with y = 0.20, 0.50, 0.80. The results allow the deduction of osmotic coefficients. The experimental results are compared with the predictions of the Zdanovskii-Stokes-Robinson (ZSR), Robinson and Stokes (RS), Lietzke and Stoughton (LS II), Reilly-Wood-Robinson (RWR) mixing rules and the Pitzer model. From these measurements, the Pitzer mixing ionic parameters are determined and used to predict the solute activity coefficients in the mixture. The excess Gibbs energy is also determined.