Quantification of high temperature stability of mineral wool for fire-safe insulation

• Published in: Journal of non-crystalline solids Vol. 622; p. 122680
• Main Authors: Jensen, Peter G., Belmonte, Louise, Solvang, Mette, Yue, Yuanzheng
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.12.2023
• Subjects: Crystallization; Glass; Glass wool; High temperature stability; Shrinkage; Stone wool; High temperature stability; Glass wool; Shrinkage; Stone wool; Glass; Crystallization
• ISSN: 0022-3093; 1873-4812
• DOI: 10.1016/j.jnoncrysol.2023.122680

•High temperature stability of mineral wool was quantified by hot stage microscopy.•The origin of its high temperature stability (HTS) was revealed by DSC and XRD.•The first-stage shrinking of mineral wool during heating is due to viscous flow.•Fiber crystallization is a key for the high temperature stability of mineral wool. Mineral wool, particularly stone wool, is a widely applied thermal insulation material that plays a critical role both in saving energy and in slowing the spread of fire in buildings owing to its high-temperature stability (HTS). However, so far there has been a lack of a universal method to accurately quantify HTS of mineral wool on a small scale. Here, we established a universal method, which is based on measuring the variation of the silhouette area of a cylindrical wool fiber pellet during heating by a hot-stage microscope. Using this method, we detected two main stages of shrinking: 1) the first-stage shrinking related to viscous deformation; 2) the second-stage shrinking caused by melting. Minimizing the first stage shrinking is the key to ensure the fire barrier role of stone wool. The origin of the HTS differences among different types of wool products was clarified by X-ray diffraction, differential scanning calorimetry and thermal expansion.