Synthesis of functionalised indolines by radical-polar crossover reactions
Functionalised indolines have been prepared by treating tetrathiafulvalene (TTF) with 2-(N-acyl-N-allylamino)benzenediazonium tetrafluoroborates. N-Benzoyl-protected substrates afford complex reaction mixtures due to competing radical cyclisation onto the benzoyl group, Acetamides react more efficie...
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Published in | Journal of the Chemical Society, Perkin Transactions 1 no. 10; pp. 1549 - 1558 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
CAMBRIDGE
Royal Soc Chemistry
1997
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Subjects | |
Online Access | Get full text |
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Summary: | Functionalised indolines have been prepared by treating tetrathiafulvalene (TTF) with 2-(N-acyl-N-allylamino)benzenediazonium tetrafluoroborates. N-Benzoyl-protected substrates afford complex reaction mixtures due to competing radical cyclisation onto the benzoyl group, Acetamides react more efficiently affording good yields of product alcohols when the reactions are carried out in moist acetone. |
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ISSN: | 0300-922X 1364-5463 |
DOI: | 10.1039/a607060d |