A NEW CHEMICAL AMPLIFICATION RESIST SYSTEM BASED ON NOVOLAC AND T-BOC PROTECTED PHOSPHAZENE AS A DISSOLUTION INHIBITOR

• Published in: Journal of Photopolymer Science and Technology Vol. 5; no. 1; pp. 67 - 77
• Main Authors: AHN, KWANG-DUK, KANG, JONG-HEE, KIM, SEONG-JU, PARK, BYUNG-SUN, PARK, CHAN-EON, PARK, CHUN-GEUN
• Format: Journal Article
• Language: English
• Published: Hiratsuka The Society of Photopolymer Science and Technology(SPST) 1992; Japan Science and Technology Agency
• ISSN: 0914-9244; 1349-6336
• DOI: 10.2494/photopolymer.5.67

t-BOC protected hexakis(4-t-BOC-phenoxy)cyclotriphosphazene, TBP, was synthesized from a semiinorganic phosphazene compound and its acid-catalyzed thermal deprotection was utilized in the design of a three-component positive resist system based on the combined principles of chemical amplification and dissolution inhibition. The new resist system, PTPNS(NR/TBP/PAG), is formulated with novolac resin (NR), TBP and a photoacid generator (PAG). The dissolution characteristics of PTPNS in alkaline development are ideally suited for application to positive type resists which are based on a dissolution inhibition mechanism. The t-BOC protected TBP of the PTPNS resist system effectively acts as an acid-labile dissolution inhibitor of novolac resin when TBP concentration is more than 10% by weight. As a representative, PTPNS(100/15/5) (by weight parts) exhibited high sensitivity in the range of 20 to 25mJ/cm2 with contrast of 5 after exposure at 250nm light and PEB treatment at 100 to 130°C. Appropriately formulated PTPNS resist rendered positive-tone patterns down to sub-half micron with high sensitivity when the resist was exposed to KrF excimer laser or electron beam and developed with 2.38wt% tetramethylamonium hydroxide solution.