Reactions of aqueous copper acetate with triethylamine and 3,5-dimethylpyrazole

The dissolution of aqueous copper acetate in tetrahydrofuran gives the Cu₂(μ-OOCMe)₄(thf)₂ complex (1), and its reaction with triethylamine in the presence of acetic acid yields “[Cu₂(μ-OOCMe)₄[μ-OOCMe(HNEt₃)]” n polymer (2). Complexes 1 and 2 react with 3,5-dimethylpyrazole to form Cu(Hdmpz)₂(OOCMe...

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Published inRussian journal of inorganic chemistry Vol. 55; no. 5; pp. 714 - 726
Main Authors Perova, E. V, Yakovleva, M. A, Baranova, E. O, Anan'ev, I. V, Nefedov, S. E
Format Journal Article
LanguageEnglish
Published Dordrecht Dordrecht : SP MAIK Nauka/Interperiodica 2010
SP MAIK Nauka/Interperiodica
Subjects
Chemistry
Chemistry and Materials Science
Coordination Compounds
Inorganic Chemistry
Mother Liquor
Binuclear Complex
Carboxylate Anion
Pyrazolate
Copper Acetate
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Summary:The dissolution of aqueous copper acetate in tetrahydrofuran gives the Cu₂(μ-OOCMe)₄(thf)₂ complex (1), and its reaction with triethylamine in the presence of acetic acid yields “[Cu₂(μ-OOCMe)₄[μ-OOCMe(HNEt₃)]” n polymer (2). Complexes 1 and 2 react with 3,5-dimethylpyrazole to form Cu(Hdmpz)₂(OOCMe)₂ (3) and Cu₂(μ-OOCMe)₄(Hdmpz)₂ (4), respectively. The structures of complexes 1-4 and that of solvate 4 × 0.5C₆H₆ (5) are determined by X-ray diffraction.
Bibliography:http://dx.doi.org/10.1134/S0036023610050104
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023610050104