Parametric analysis of a modified ammonia-hydrogen-electricity cogeneration system

• Published in: International journal of hydrogen energy Vol. 56; pp. 219 - 231
• Main Authors: Kang, Zongyao, Liu, Bin, She, Xiaohui, Liu, Wei, Huang, Jingzhong, Wang, Kaihui
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 22.02.2024
• Subjects: Ammonia-hydrogen-electricity cogeneration system; Brayton cycle; Iodine sulfur cycle; Nuclear heat for hydrogen (ammonia) production; Ammonia-hydrogen-electricity cogeneration system; Nuclear heat for hydrogen (ammonia) production; Brayton cycle; Iodine sulfur cycle
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2023.12.130

In this paper, a novel ammonia-hydrogen-electricity cogeneration system is developed. To mitigate the cost associated with hydrogen storage and transportation in later stages, the proposal is to utilize high-temperature ammonia production instead of conventional hydrogen production. A comparative analysis between ammonia and transportation for hydrogen is conducted to assess cost efficiencies. To improve the system efficiency, a supercritical CO2 Brayton cycle is applied as the power generation cycle. This choice exhibits superior parameter compatibility with the system compared to the Rankine cycle. The study scrutinizes the impacts of different energy utilization sequences and varying process parameters of the power generation cycle on the system's performance to ascertain the most optimal configuration. The results indicate that the Brayton cycle is more suitable for integration with the nuclear-IS thermochemical hydrogen production system, significantly enhancing the power generation capacity of the ammonia-hydrogen-electricity cogeneration system. These improvements result in 18.8 % increase in power generation efficiency and a 9.3 % boost in overall energy efficiency of the system. Subsequent to this enhancement, the system attains an impressive energy efficiency of 47.0 % along with a system exergy efficiency of 63.4 %. This study introduces an innovative approach for optimizing and enhancing the energy efficiency of a cogeneration system by employing nuclear energy as a high-temperature heat source for hydrogen (ammonia) production. •A novel ammonia-hydrogen-electric cogeneration system is developed.•The system bolsters efficiency by 9.3 % through a synergistic Brayton cycle coupling.•Conducted an assessment and comparison of the transportation and storage expenses associated with hydrogen and ammonia.