Frustrated Lewis pair engineering on ceria to improve methanol oxidation activity of Pt for direct methanol fuel cell applications

• Published in: International journal of hydrogen energy Vol. 48; no. 15; pp. 5953 - 5960
• Main Authors: Xu, Guodong, Lei, Yun, Wu, Keyu, Lv, Rongguan, Li, Jing, Sun, Xiujuan, Cai, Weiwei
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 19.02.2023
• Subjects: Direct methanol fuel cell; Frustrated Lewis pair; Methanol oxidation; Negatively charged sites; Plasma-phosphating combing strategy; Direct methanol fuel cell; Frustrated Lewis pair; Negatively charged sites; Methanol oxidation; Plasma-phosphating combing strategy
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2022.11.188

Practical application of direct methanol fuel cell (DMFC) technology is greatly hindered by the strong dependence of anodic methanol oxidation reaction (MOR) on precious Pt based catalyst and the unsatisfying performance of Pt. Therefore, increasing the utilization and the catalytic performance of Pt toward MOR in DMFC is urgent. Here in this work, CeO2 is modified via a plasma-phosphating combing strategy and is invited as Frustrated Lewis Pair to assist the catalytic MOR process on Pt sites. Simultaneously, the plasma-phosphating combing strategy leads to negatively charged sites on CeO2 surface, which can be functioned as host for Pt anchoring, facilitating the even dispersion of Pt nanocrystals. Besides, this strategy also has an effect on the Ce3+/Ce4+ ratio and vacancy oxygen ratio on CeO2 surface, which are critical to the adsorbed OH generation and anti-CO poisoning ability, thus boosting the MOR catalytic activity of Pt. DMFC device therefore exhibits ca. 30% maximum power density enhancement compared with the commercial Pt/C based DMFC. Ce–P LFP, which is highly active toward water dissociation reaction, is constructed in CeO2 substrate via the plasma-phosphating combing strategy for Pt loading and the MOR activity is significantly improved with the DMFC performance enhanced by 30%. [Display omitted] •Ce–P LFP is constructed substrate via the plasma-phosphating combing strategy.•Pt nanoparticles can be evenly distributed on Ce–P LFP rich CeO2 substrate.•DMFC performance is enhanced by ca. 30%.