Crystal structures, Hirshfeld surface analysis, thermal behavior and dielectric properties of a new organic–inorganic hybrid [C6H10(NH3)2]Cu2Cl8

• Published in: Journal of molecular structure Vol. 1149; pp. 414 - 425
• Main Authors: Salah, Najet, Hamdi, Besma, Bouzidia, Nabaa, Salah, Abdelhamid Ben
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 05.12.2017
• Subjects: AC conductivity; Copper(II) complex; Dielectric properties; Electrical impedance spectroscopy; Copper(II) complex; Electrical impedance spectroscopy; Dielectric properties; AC conductivity
• ISSN: 0022-2860; 1872-8014
• DOI: 10.1016/j.molstruc.2017.08.002

A novel organic-inorganic hybrid sample [C6H10(NH3)2]Cu2Cl8 has been prepared under mild hydrothermal conditions and characterized by single crystal X-ray diffraction, Hirshfeld surface analysis, FT-IR,NMR and UV–Vis spectroscopies, differential scanning calorimetric and dielectric measurement. It is crystallized in the monoclinic system with P21/c space group. The cohesion and stabilization of the structure are provided by the hydrogen bond interactions, (NH⋯Cl and CH⋯Cl), between [C6H10(NH3)2]2+ cation and [Cu2Cl8]2- anion. The Hirschfeld surface analysis has been performed to explore the behavior of these weak interactions. The presence of different functional groups and the nature of their vibrations were identified by FT-IR and Solid state NMR. The thermal study revealed that this compound undergoes two structural phase transitions around 353 and 376 K. Electrical measurements of our compounds have been investigated using complex impedance spectroscopy (CIS) in the frequency and temperature range 331–399 K and 200 Hz–5 MHz, respectively. The AC conductivity is explained using the correlated barrier hopping model (CBH) conduction mechanism. The nature of DC conductivity variation suggests Arrhenius type of electrical conductivity. A relationship between crystal structure and ionic conductivity was established and discussed. Finally, the real and imaginary parts of the permittivity constant are analyzed with the Cole–Cole formalism and the optical spectra indicate that the compound has a direct band gap (3.14 eV) due to direct transition. The wide band gap is due to low defect concentration in the grown crystal, which is more useful for the laser/optical applications. [Display omitted] •The crystal packing of the [C6H10(NH3)2]Cu2Cl8 is governed by NH⋯Cl and CH⋯Cl interactions.•The title crystal undergoes two structural phase transitions.•The conduction mechanism that provide the conduction in this material is determined.•The optical property was studied by UV–vis absorption.