Enhanced water permeability of hollow fiber composite reverse osmosis membrane using porous α-cellulose/polysulfone hollow fiber membrane as the substrate

• Published in: Textile research journal Vol. 93; no. 19-20; pp. 4433 - 4450
• Main Authors: Li, Hongbin, Fan, Mengjie, Li, Linmao, Ma, Sisi, Shi, Wenying, Liu, Jie
• Format: Journal Article
• Language: English
• Published: London, England SAGE Publications 01.10.2023; Sage Publications Ltd
• Subjects: Aqueous solutions; Cellulose; Contact angle; Distillation; Fiber composites; Hollow fiber membranes; Hydrofluorocarbons; Hydrophilicity; Membrane permeability; Membranes; Methylene blue; Osmosis; Performance degradation; Permeability; Polysulfone; Polysulfone resins; Rejection rate; Reverse osmosis; Salt rejection; Scanning electron microscopy; Separation; Sodium chloride; Substrates; Vacuum distillation; Wet spinning; reverse osmosis; Hollow fiber membrane; cellulose; permeability; hydrophilicity
• ISSN: 0040-5175; 1746-7748
• DOI: 10.1177/00405175231176860

The hollow fiber composite (HFC) reverse osmosis (RO) membrane with a special self-supporting structure has attracted a great deal of attention in the fields of separation and purification. However, low permeability is an urgent problem restricting its wide application. A porous polysulfone (PSF) hollow fiber support membrane was fabricated through the dry–wet spinning technique and hydrophilic α-cellulose © powder was incorporated in the PSF membrane matrix to improve the membrane’s water permeability. The HFC RO membrane was prepared via the interfacial polymerization process on the inner surface of the C/PSF support membrane. The membrane morphology and surface hydrophilicity were evaluated through scanning electron microscopy observation and dynamic water contact angle (WCA) measurement. The effects of α-cellulose incorporation on the separation performance of PSF hollow fiber membranes and HFC RO membranes were investigated. The results showed that the surface hydrophilicity and water permeability of the PSF membrane were significantly improved after the introduction of α-cellulose. The WCA of the modified PSF support membrane decreased from 84.6° for the neat PSF membrane to 70.25°, and the pure water flux can reach a maximum value of 102.1 L/(m2 · h) (0.1 Mpa), which was 1.3 times that of the pristine membrane. The HFC RO membrane using the hydrophilic modified PSF membrane as the substrate exhibited an enhanced water flux of 15.6 L/(m2 · h) and, meanwhile, the membrane salt rejection remained above 97.6% (1.0 wt% NaCl aqueous solution, 0.7 Mpa). The HFC RO membrane showed extremely high rejection rates (99%) for different dyes (congo red and methylene blue). No obvious performance deterioration was observed for the HFC RO membrane during continuous vacuum membrane distillation (VMD) experiments for 60 h.