Effect of SiC whiskers on the mechanical and ablation performances of Cu modified C/C composite

• Published in: Ceramics international Vol. 48; no. 4; pp. 5369 - 5376
• Main Authors: Wang, Pei, Wei, Fengchun, Zhang, Hongbo, Yin, Jian, Hao, Zhenhua, Zhou, Jiwei
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.02.2022
• Subjects: Ablation mechanism; Carbon/carbon composite; Mechanical strength; SiC whiskers; Ablation mechanism; SiC whiskers; Carbon/carbon composite; Mechanical strength
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2021.11.080

To attain a novel ablation-resistant composite for ultra-high temperature structure application, SiC whiskers reinforced C/C–Cu (C/C–SiCW–Cu) composite was fabricated via chemical vapor deposition and infiltration technologies. Microstructure, mechanical and anti-ablation performances of C/C–SiCW–Cu composite were investigated and compared with those of C/C–SiC–Cu composite. The results show C/C–SiCW–Cu composite has significant advantages in compactness, flexural strength and ablation resistance. Because SiC whisker has a high specific surface area, C/C–SiCW–Cu composite has higher capillary force than C/C–SiC–Cu composite for the infiltration of Cu alloy. Meanwhile, the reinforcement of SiC whisker retards the SiC/Cu interfacial debonding during fracture failure process. Schematic models were built to clarify the structural evolution of ablated surface during oxyacetylene ablation tests, and anti-ablation process of C/C–SiCW–Cu composite can be described: forming a compact SiO2 layer, SiC whiskers pinning anti-ablation layer and Cu alloy transpiration cooling effect.