Phospho-silicate and silicate layers modified by hydroxyapatite particles

• Published in: Journal of molecular structure Vol. 744; pp. 589 - 595
• Main Authors: Rokita, M., Brożek, A., Handke, M.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 03.06.2005
• Subjects: Hydroxyapatite layers; Infrared spectra; Phospho-silicate layers; Sol–gel method; Phospho-silicate layers; Infrared spectra; Sol–gel method; Hydroxyapatite layers
• ISSN: 0022-2860; 1872-8014
• DOI: 10.1016/j.molstruc.2005.01.060

Common used metal materials do not ensure good connection between an implant and biological neighbourhood. Covering implants by thin silicate or phosphate layers enable to improve biological properties of implants and create conditions for producing the non-concrete bonding between the implant and tissue. The project includes preparing silicate sols of different concentrations and proper (powder) fraction of synthetic as well as natural ox hydroxyapatite, depositing the sol mixed with hydroxyapatite onto the base material (metal, ceramic carbon) and heat treatment. Our work includes also preparation of phospho-silicate layers deposited onto different base materials using sol–gel method. Deposited sols were prepared regarding composition, concentration and layer heat treatment conditions. The prepared layers are examined to determine their phase composition (XRD, IR spectroscopy methods), density and continuity (scanning microscopy with EDX methods). Biological activity of layers was evaluated by means of estimation of their corrosive resistance in synthetic body fluids (‘in vitro’ method) and of bone cells growth on the layers surface. Introducing hydroxyapatite to the layer sol should improve connection between tissue and implant as well as limit the disadvantageous, corrosive influence of implant material (metal) on the tissue.