Synthesis and physical properties of polyfluoro-acridines bearing perfluoroalkyl chains

Here we describe the synthesis of polyfluoro-acridines functionalised with perfluoro-alkyl and perfluoro-alkoxy chains, obtained by Ullmann coupling reaction or aromatic nucleophilic substitution. Surface wettability of PMMA is changed by doping with tetrafluoro-perfluorodecyl-acridine, as shown by...

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Bibliographic Details
Published inJournal of fluorine chemistry Vol. 129; no. 4; pp. 294 - 300
Main Authors Papagni, Antonio, Campiglio, Paolo, Campione, Marcello, Del Buttero, Paola, Mani, Antonio, Miozzo, Luciano, Tonelli, Enrico
Format Journal Article
LanguageEnglish
Published LAUSANNE Elsevier B.V 01.04.2008
Elsevier
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Perfluoro-alkyl chain
Phase contrast AFM
Physical Sciences
Science & Technology
Surface segregation
Tetrafluoro-acridine
Phase contrast AFM
Surface segregation
Tetrafluoro-acridine
Perfluoro-alkyl chain
surface segregation
STATE EMITTING SYSTEMS
tetrafluoro-acridine
perfluoro-alkyl chain
phase contrast AFM
BUILDING-BLOCKS
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Summary:Here we describe the synthesis of polyfluoro-acridines functionalised with perfluoro-alkyl and perfluoro-alkoxy chains, obtained by Ullmann coupling reaction or aromatic nucleophilic substitution. Surface wettability of PMMA is changed by doping with tetrafluoro-perfluorodecyl-acridine, as shown by AFM and contact angle measurements.
ISSN:0022-1139
1873-3328
DOI:10.1016/j.jfluchem.2008.01.005