Influence of electric field strength on structure, microstructure, and electrical properties of flash sintered 8% mol Yttria-stabilized zirconia as a solid oxide fuel cell electrolyte

• Published in: Ceramics international Vol. 47; no. 14; pp. 20220 - 20229
• Main Authors: Mohebbi, H., Mirkazemi, S.M.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.07.2021
• Subjects: Electric field; Flash sintering; Ionic conduction; SOFC electrolyte; Space charge model; Ionic conduction; SOFC electrolyte; Electric field; Space charge model; Flash sintering
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2021.04.029

To study the effect of electric field on the characteristics of flash sintered materials, 8% mol. Yttria-stabilized zirconia (8YSZ) was isothermally flash sintered under various electric field strengths as a solid oxide fuel cell (SOFC) electrolyte. Structural, microstructural, and electrical characteristics were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Electrochemical impedance spectroscopy (EIS), respectively. Results show that the electric field did not affect the relative density of flash sintered 8YSZ. Electric fields stronger than 300 V cm−1, however, transformed the cubic structure to tetragonal. Microstructural studies show that the average grain size of samples is independent of the applied electric field strength. Electrochemical impedance spectroscopy showed changes in the grain boundary characteristics upon using the electric field for flash sintering. Oxygen vacancy concentration in the grain boundary of flash sintered samples was more than ten times higher than conventionally sintered ones, which improved the conductivity in flash sintered samples.