Investigation of Hydrogen Storage Characteristics of MgH2 Based Materials with Addition of Ni and Activated Carbon

• Published in: Inorganics Vol. 8; no. 2; p. 12
• Main Authors: Grigorova, Eli, Nihtianova, Diana, Tsyntsarski, Boyko, Stoycheva, Ivanka
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.02.2020
• Subjects: Absorption; Activated carbon; Additives; Argon; Ball milling; carbon materials; Composite materials; Electron diffraction; Hydrogen; Hydrogen storage; Hydrogenation; Low pressure; Magnesium; mg-based composites; Nickel; Polyethylene; Polyethylenes; Polyolefins; Resource recovery; sorption kinetics
• ISSN: 2304-6740; 2304-6740
• DOI: 10.3390/inorganics8020012

Magnesium-based materials are promising as hydrogen storage media due to their high theoretical hydrogen absorption capacity, abundance and low price. The subject of this study are the hydrogen sorption characteristics of the composites 80 wt % MgH2-15 wt % Ni-5 wt % activated carbon (synthesized from polyolefin wax, a waste product of polyethylene production at low pressure which will be denoted further in the text as POW) and 90 wt % MgH2-5 wt % Ni-5 wt % POW, prepared by ball milling under argon atmosphere. Structure, phase and surface composition of the samples before and after hydrogenation are determined by XRD and TEM. The maximum absorption capacity value of the composites at a temperature 573 K and after 60 min. of hydrogenation are 5.3 wt % H2 for the material with higher Ni content and 5.5 wt % H2 for the other sample. The presence of both additives—nickel and activated carbon derived from POW—has a positive impact on hydrogenation kinetics and the capacity achieved. The results from TEM characterization, e.g., the polycrystalline SAED (selected area electron diffraction) show the presence of graphite, Mg and monoclinic Mg2NiH4.